Chuck has his pick of the best CIA agents for an undercover operation, but he only has one girl in mind for the job: Sarah. Casey, Morgan and Awesome team up to help Chuck win her back. Recurring guest star BRANDON ROUTH appears as Daniel Shaw.
Chuck learns that his latest solo mission will be a final test to see if he is ready to be a spy. Chuck needs to put everything he has learned into action to avoid going back to his old life while Sarah and Shaw (recurring guest star BRANDON ROUTH) observe his every move.
Casey carries out a side mission for his old commanding officer, Colonel James Keller (guest star Robert Patrick - Terminator 2: Judgment Day, The Unit, The X Files), but it leads to Casey committing treason. When Chuck learns the dark truth about Col. Keller, he and Sarah set out to break Casey out of jail and clear his name. Meanwhile, Awesome's plan to keep Ellie out of danger gets more difficult when she gets her dream fellowship.
Chuck feels like his life is falling apart when he can't flash and gets left behind on a mission. While Shaw (recurring guest star BRANDON ROUTH), Sarah and Casey go on without him, Chuck finds himself in a sticky situation back at the base. DIEDRICH BADER (The Drew Carey Show, Batman: The Brave and the Bold) guest stars.
Chuck promises to cook dinner for Hannah (recurring guest star KRISTIN KREUK), Ellie and Awesome, but first, for his latest mission, he must assume the identity of the world's most dangerous assassin. Meanwhile, Sarah is determined to keep her relationship with Shaw (recurring guest star BRANDON ROUTH) strictly professional.
Chuck and Hannah (recurring guest star KRISTIN KREUK) unexpectedly become part of agent Daniel Shaw's (recurring guest star BRANDON ROUTH) latest mission. Much to Sarah's chagrin, she gets paired with Shaw, who seems to be trying to get close to her. Meanwhile, Morgan and Ellie continue their mission to get to the bottom of Chuck's secretive and strange behavior.
Chuck juggles his two lives as he trains new Nerd Herder Hannah (recurring guest star KRISTIN KREUK - Smallville) and gets his very own asset who is caught up with The Ring. Chuck thinks he can handle his asset all on his own but Sarah and Casey feel the need to intercede. Meanwhile, Awesome must lie to Ellie when she starts to ask questions about Chuck. And Morgan, Jeff and Lester do some recon work to learn more about Hannah.
CIA agent Daniel Shaw (recurring guest star BRANDON ROUTH) assigns Chuck to his first solo mission in Paris, ignoring Sarah and Casey's wishes. During the flight to France, Chuck befriends Hannah (recurring guest star KRISTIN KREUK - Smallville) and flashes on another passenger ? the imposing Hugo Panzer (guest star STONE COLD STEVE AUSTIN - WWE Smackdown!). Meanwhile, Casey helps Morgan battle Jeff and Lester for control of the Buy More.
When Awesome is mistaken for a super spy by the evil Sydney Price (guest star ANGIE HARMON - Law & Order), Chuck must become Awesome's handler and show him the spy ropes. While on a mission for The Ring, they meet the mysterious Daniel Shaw (recurring guest star BRANDON ROUTH - Superman Returns). Meanwhile, Morgan gets promoted to assistant manager at the Buy More and must deal with the latest hijinks from Jeff and Lester.
Though Chuck tries to always protect his family from his spy life, he can't stop Ellie and Awesome from stumbling into an international incident. Chuck must use his relationship with Awesome to protect a visiting dictator, Premier Goya (guest star ARMAND ASSANTE - American Gangster), who is the target of an assassination. While Awesome is excited about the prospect of being a spy, Chuck is more concerned with Awesome and Ellie's safety.
Chuck gets a new mission when Sarah's best friend comes through town with her fiancé, Karl (guest star VINNIE JONES - Snatch, X-Men: The Last Stand). But things get complicated when, while on the mission, Chuck wants to hash out his and Sarah's relationship problems. Can he learn to keep his emotions in check? Meanwhile, Morgan finds himself in trouble when he lies to Jeff and Lester.
At the end of season two, Chuck was transformed into the Intersect 2.0 after receiving another data download into his brain. This time, he not only knows government secrets, but he is equipped with the knowledge and coordination of deadly fight skills. Now that Chuck has proven himself to be an asset, and knows Kung-Fu, he finally has the potential to become a real agent. There's just one problem ? his emotions. Chuck must keep them under control in order to protect himself and the people around him.
Zachary Levi stars as Chuck Bartowski, the Buy More electronics store computer geek who unwittingly becomes the government's most vital secret agent. Chuck's third season features more missions, more action and guest stars galore, including Brandon Routh as CIA Agent Daniel Shaw; Kristin Kreuk as Hannah, a potential love interest for Chuck; Angie Harmon, Robert Patrick, Armand Assante; Steve Austin; and Vinnie Jones.
When Ellie and Awesome's wedding day finally arrives, Chuck must save Ellie's life and her big day from being ruined by Ted Roark (recurring guest star Chevy Chase) and Fulcrum. Recurring guest stars also include Morgan Fairchild, Bruce Boxleitner, Tony Hale and Scott Bakula.
When Chuck and Sarah go AWOL to rescue Chuck's father, Steve (recurring guest star Scott Bakula), they discover that spending time together without any surveillance allows for unchartered chemistry. As the two get closer, Casey zeroes in on their hidden location. Meanwhile, Morgan becomes the pariah of the Buy More after mistakenly getting Emmett (recurring guest star Tony Hale) promoted.
After Chuck's father, Steve (recurring guest star Scott Bakula), is kidnapped by Fulcrum, Chuck learns the only chance he has to find him is by putting his trust and life into the hands of the person he trusts the least — his ex-girlfriend Jill (recurring guest star Jordana Brewster). Meanwhile, the Buy More team tries to sabotage Emmett's (recurring guest star Tony Hale) corporate evaluation.
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