Superman encounters Bizarro (also voiced by series star Tim Daly), an imperfect genetic double of the Man of Steel, who tries to take Superman's place as Metropolis' hero.

Volcana (guest star voice Peri Gilpin), a villainess who can control fire, goes on a crime spree stealing valuable artifacts while on the run from government agents and Superman (series star Tim Daly).

Mxyzptlk (recurring guest star voice Gilbert Gottfried) gets into trouble with the rulers of his planet--and Superman--when he enlists Bizarro's (series star Tim Daly) help to wreak havoc on Earth.

Young Clark Kent (series star Tim Daly) discovers the truth about his interplanetary heritage. Upon reaching adulthood, he assumes the identity of Superman, the Man of Steel, in the city of Metropolis. Part 2 of 3.

Superman (series star Tim Daly) decides to release Mala (recurring guest star voice Leslie Easterbrook), a Kryptonian criminal, from the Phantom Zone. When Mala continues her criminal activity, Superman tries to send her back. But Mala escapes with the Phantom Zone Projector and releases Krypton's most notorious traitor, Jax-Ur (recurring guest star voice Ron Perlman). Part 1 of 2

The View: Tim Daly, Part 1

The View: Tim Daly, Part 2

ABC.com Exclusive: Take a look at Patrick Stinson's interview with Kate Walsh and Tim Daly of Private Practice.

ABC.com Exclusive: Take a look at Patrick Stinson's interview with Kate Walsh and Tim Daly of Private Practice.

ABC.com Exclusive: Take a look at Patrick Stinson's interview with Kate Walsh and Tim Daly of Private Practice.